Widom and extrema lines as criteria for optimizing operating conditions in supercritical processes

نویسندگان

چکیده

This work focuses on the supercritical region of fluid phase equilibria, just above critical point. It is already known that in this area, two different zones can be distinguished, one where fluids (SCFs) have liquid-like properties, and other SCFs gas-like properties; these being delimited by Widom extrema lines. draws attention to lines, indicating they may serve guide choice process operating conditions. Three simple approaches for prediction line lines binary mixtures involving CO 2 any composition are proposed. The with eight very common organic cosolvents, as well water, predicted compositions (5%, 10% 50% cosolvent). • Simple proposed predicting mixtures. 9 at compositions. stresses conditions must outside transitory zone.

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ژورنال

عنوان ژورنال: Journal of Supercritical Fluids

سال: 2022

ISSN: ['1872-8162', '0896-8446']

DOI: https://doi.org/10.1016/j.supflu.2022.105587