Widom and extrema lines as criteria for optimizing operating conditions in supercritical processes
نویسندگان
چکیده
This work focuses on the supercritical region of fluid phase equilibria, just above critical point. It is already known that in this area, two different zones can be distinguished, one where fluids (SCFs) have liquid-like properties, and other SCFs gas-like properties; these being delimited by Widom extrema lines. draws attention to lines, indicating they may serve guide choice process operating conditions. Three simple approaches for prediction line lines binary mixtures involving CO 2 any composition are proposed. The with eight very common organic cosolvents, as well water, predicted compositions (5%, 10% 50% cosolvent). • Simple proposed predicting mixtures. 9 at compositions. stresses conditions must outside transitory zone.
منابع مشابه
The Widom line as the crossover between liquid-like and gas-like behaviour in supercritical fluids
According to textbook definitions1, there exists no physical observable able to distinguish a liquid from a gas beyond the critical point, and hence only a single fluid phase is defined. There are, however, some thermophysical quantities, having maxima that define a line emanating from the critical point, named ‘the Widom line’2 in the case of the constant-pressure specific heat. We determined ...
متن کاملSuucient Conditions for Multiply Constrained Extrema
on a Hilbert space H. We derive suucient conditions for I to have a strong local minimum at a point y subject to the n constraints J i = 0.
متن کاملDynamics of the contacts reveals Widom lines for jamming
We experimentally study the vicinity of the jamming transition by investigating the statics and the dynamics of the contact network of a horizontally shaken bi-disperse packing of photo-elastic discs. Compressing the packing very slowly, while maintaining a mechanical excitation, yields a granular glass, namely a frozen structure of vibrating grains. In this glass phase, we observe a remarkable...
متن کاملSearching for the Tracy-Widom distribution in nonequilibrium processes.
While originally discovered in the context of the Gaussian unitary ensemble, the Tracy-Widom distribution also rules the height fluctuations of growth processes. This suggests that there might be other nonequilibrium processes in which the Tracy-Widom distribution plays an important role. In our contribution we study one-dimensional systems with domain wall initial conditions. For an appropriat...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Journal of Supercritical Fluids
سال: 2022
ISSN: ['1872-8162', '0896-8446']
DOI: https://doi.org/10.1016/j.supflu.2022.105587